Not a big shot in the gunnery world (6)
I believe the answer is:
pellet
'shot in the gunnery world' is the definition.
'pellet' can be an answer for 'shot' (synonyms). I'm not certain of the 'in the gunnery world' bit.
I cannot understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for pellet that I've seen before include "Lightweight bullet" , "Small pill" , "A piece of shot from cartridge" , "Piece of shot for gun" , "Small rounded mass" .)