Not a fit face for an assumption of pretence (11)
I believe the answer is:
affectation
'pretence' is the definition.
(affectation is a kind of pretence)
'not a fit face for an assumption' is the wordplay.
'not a fit face' can be anagrammed to 'AFFECTATION'.
But, I'm unsure how the anagram is indicated.
'of' acts as a link.
Can you help me to learn more?
(Other definitions for affectation that I've seen before include "unnatural appearance" , "retence" , "Show evidence of" , "Deliberate pretence" .)