Not accustomed to being unemployed? (6)
I believe the answer is:
unused
I believe this clue is a double definition.
'not accustomed to' is the first definition.
(I've seen this before)
'unemployed?' is the second definition.
(thesaurus)
'being' is the link.
(Other definitions for unused that I've seen before include "Extra" , "Mint, virgin" , "idle" , "hadn't been exploited" , "Not utilised" .)