Not all benevolence may be affectionate! (4)
I believe the answer is:
love
'not all' is the definition.
'love' can be an answer for 'all' (I've seen this before). I am not sure about the 'not' bit.
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for love that I've seen before include "Nothing for the Williams sisters?" , "Romantic feeling" , "Feel great affection for" , "Nil score in 19" , "Zero score, dear" .)