Not exactly wily, but unctuous (4)
I believe the answer is:
oily
'unctuous' is the definition.
(I know that unctuous can be written as oily)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for oily that I've seen before include "Smoothly ingratiating" , "Smooth, ingratiating" , "Unpleasantly ingratiating" , "Like a lot of fish" , "Smarmy" .)