Not, you say, the green collar (4)
I believe the answer is:
ruff
'collar' is the definition.
(I know that ruff is a type of collar)
I don't understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for ruff that I've seen before include "Jacobean neckwear" , "Elizabethan or Jacobean neck adornment" , "High tight collar" , "Type of collar" , "Starched frill; fish" .)