Observe with sly glance on turning (4)
I believe the answer is:
keep
'observe' is the definition.
('keep' can be a synonym of 'observe')
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for keep that I've seen before include "Retain possession of" , "Hold - part of castle" , "Save" , "Retain or care for" , "Continue" .)