Of characters, a villainous one in the past (4)
I believe the answer is:
iago
'of characters a villainous' is the definition.
I can't judge whether this definition defines the answer.
'one in the past' is the wordplay.
'one' becomes 'i' (Roman numeral).
'in the past' becomes 'ago' ('ago' can be a synonym of 'in the past').
'i'+'ago'='IAGO'
Can you help me to learn more?
(Other definitions for iago that I've seen before include "stage villain" , "Othello's enemy" , "Advisor to soldier" , "Shakespeare's jealous villain" , "Othello's treacherous officer" .)