Old instrument of temptation (7)
I believe the answer is:
serpent
'old instrument' is the definition.
'serpent' can be an answer for 'instrument' (serpent is a kind of instrument). I'm unsure of the 'old' bit.
I don't understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for serpent that I've seen before include "the first lady found beguiling" , "Snake - old wind instrument" , "exhibit at zoo" , "Limbless reptile" , "Early wind instrument" .)