Old man’s code word for a pee (4)
I believe the answer is:
papa
I believe this is a double definition.
'old man's' is the first definition.
(synonyms)
'code word for a pee' is the second definition.
(NATO phonetic alphabet codeword for the letter P)
(Other definitions for papa that I've seen before include "Father; P (radio comms.)" , "Pop" , "Father; letter P" , "The old man" , "Mama's other half?" .)