Old Nick was enthroned on one (5)
I believe the answer is:
satan
'old nick' is the definition.
(I know that old nick can be written as Satan)
'enthroned on one' is the wordplay.
'enthroned on' becomes 'sat' (I can't explain this - if you can you should give a lot more credence to this answer).
'one' becomes 'an' (an apple is one apple).
'sat'+'an'='SATAN'
'was' acts as a link.
Can you help me to learn more?
(Other definitions for satan that I've seen before include "Old Nick, Lucifer or Beelzebub" , "Apollyon" , "Fallen archangel" , "arch-fiend" , "Diabolical figure" .)