Old-fashioned, like unfermented grape juice? (5)
I believe the answer is:
musty
This clue is a double definition.
'old-fashioned' is the first definition.
(thesaurus)
'like unfermented grape juice?' is the second definition.
(must is grape juice before fermentation)
(Other definitions for musty that I've seen before include "Frowsty" , "Smelling of mould" , "Mouldy; outdated" , "Stale and dank" , "Mouldy; stale-smelling" .)