Olympian master of arts (6)
I believe the answer is:
apollo
'olympian' is the definition.
(Greek god who lived on Mount Olympus)
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for apollo that I've seen before include "Greek god; large European butterfly" , "Greek god - US space programme dedicated to moon landings - butterfly" , "American space programme for landing men on moon" , "handsome fellow" , "Greek sungod, son of Zeus" .)