On the periphery of Chicago staffroom, elegant insomniac applied make-up (8)
I believe the answer is:
cosmetic
'make-up' is the definition.
(I've seen this before)
I cannot understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for cosmetic that I've seen before include "improving superficial appearance" , "With surface effect only" , "better looks" , "Good for appearances only" , "Beauty preparation" .)