Once more a benefit (5)
I believe the answer is:
again
'once more' is the definition.
(synonyms)
'a benefit' is the wordplay.
'benefit' becomes 'gain' (synonyms).
'a'+'gain'='AGAIN'
(Other definitions for again that I've seen before include "10 10 [AGAIN" , "One more time, encore" , "On the other hand" , "Predictably perhaps" , "Here we go ___" .)