Once tried to become obscure (9)
I believe the answer is:
recondite
'obscure' is the definition.
(synonyms)
'once tried to become' is the wordplay.
'to become' indicates an anagram.
'once'+'tried'='oncetried'
'oncetried' with letters rearranged gives 'RECONDITE'.
(Other definitions for recondite that I've seen before include "(Of knowledge) obscure" , "Enigmatic" , "Direct one to be obscure or difficult" , "Mysterious" , "Abstruse" .)