One enquiring when king and queen meet (5)
I believe the answer is:
asker
'one enquiring' is the definition.
The answer is a person as well as being a singular noun. This is suggested by the definition.
'when king and queen meet' is the wordplay.
'when' becomes 'as' (eg 'when I walked' means 'as I walked').
'king and queen' becomes 'ker' (K for King and ER for Elizabeth Regina).
'meet' says to put letters next to each other.
'as'+'ker'='ASKER'
Can you help me to learn more?
(Other definitions for asker that I've seen before include "One seeking" , "One requesting" , "beggar" , "newt" .)