One giving the chimney a brush up? (5)
I believe the answer is:
sweep
'brush up?' is the definition.
'sweep' can be an answer for 'brush' (synonyms). I am not sure about the 'up?' bit.
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for sweep that I've seen before include "clear" , "Brush clean" , "if clean, could result in a whitewash" , "Long oar" , "Clean with broom" .)