One in seat from the capital of Bulgaria (5)
I believe the answer is:
sofia
This could be a double definition.
'one in seat' is the first definition.
'Sofia' can be an answer for 'seat' (Sofia is an example). I'm not sure about the 'one in' bit.
'the capital of bulgaria' is the second definition.
(I've seen this before)
'from' acts as a link.
Can you help me to learn more?
(Other definitions for sofia that I've seen before include "capital place" , "Bulgarian city" , "seat of government" , "Foreign city" , "capital city" .)