One joins them in song (6)
I believe the answer is:
anthem
'song' is the definition.
(anthem is a kind of song)
'one joins them' is the wordplay.
'one' becomes 'an' (an apple is one apple).
'joins' is a charade indicator (letters next to each other).
'an'+'them'='ANTHEM'
'in' acts as a link.
(Other definitions for anthem that I've seen before include "Uplifting song -- the man (anag)" , "Song of praise or loyalty" , "The man for a rousing song" , "National tune" , "National hymn" .)