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One picked to appear in concert? (6)

Ross

I believe the answer is:

guitar

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'one' is the definition.
Although both the answer and definition are singular nouns, I can't understand how they can define each other.

I cannot understand how the rest of the clue works.

Can you help me to learn more?

(Other definitions for guitar that I've seen before include "Six-stringed instrument" , "Fretted string instrument" , "Popular stringed musical instrument" , "13's lute" , "Stringed instrument often played by pop groups" .)

I've seen this clue in The Sun.
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