One who guides you and me to that woman (5)
I believe the answer is:
usher
'one who guides you' is the definition.
The answer is a person as well as being a singular noun. This is suggested by the definition.
'me to that woman' is the wordplay.
'me' becomes 'us' ('us' can mean 'me' in some dialects).
'to that woman' becomes 'her' ('her' refers to a woman).
'us'+'her'='USHER'
'and' acts as a link.
Can you help me to learn more?
(Other definitions for usher that I've seen before include "Minor court official" , "One puts you in your place" , "Theatre assistant" , "Cinema or theatre worker" , "pilot" .)