One’s rapt afresh with saint and angel (9)
I believe the answer is:
patroness
'angel' is the definition.
(thesaurus)
'one's rapt afresh with saint' is the wordplay.
'afresh with' indicates an anagram.
'saint' becomes 's'.
'ones'+'rapt'='onesrapt'
'onesrapt' anagrammed with 's' makes 'PATRONESS'.
'and' acts as a link.
(Other definitions for patroness that I've seen before include "financial backer" , "Female sponsoring" , "Female benefactor" , "Charitable lady" .)