Opponent fooled on odd occasions (3)
I believe the answer is:
foe
'opponent' is the definition.
(I know that foe is a type of opponent)
'fooled on odd occasions' is the wordplay.
'on odd occasions' indicates alternate letters (letters in odd-numbered positions).
The alternating letters of 'fooled' are 'FOE'.
(Other definitions for foe that I've seen before include "Someone opposing" , "friend never!" , "Opponent" , "Am archaic enemy" , "Antagonist" .)