Optimistic desire, 1/100? (4)
I believe the answer is:
hope
'optimistic desire' is the definition.
'hope' can be an answer for 'desire' (I've seen this before). I'm not certain of the 'optimistic' bit.
I cannot understand how the rest of the clue works.
(Other definitions for hope that I've seen before include "writer" , "'. . . . springs eternal in the human breast'" , "Confident expectation" , "Trustful expectation" , "Feeling of expectant desire" .)