Orderly in quite a big way (4)
I believe the answer is:
tidy
'orderly' is the definition.
(similar in meaning)
I don't understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for tidy that I've seen before include "Shipshape" , "In apple-pie order" , "small container in which odds and ends are kept" , "Businesslike" , "Fairly big - orderly" .)