Orderly periodically gets masters again (8)
I believe the answer is:
relearns
'masters again' is the definition.
The definition and answer can be both related to thinking as well as being verbs in their -s form.
Maybe you can see an association between them that I can't see?
'orderly periodically gets' is the wordplay.
'periodically' indicates alternate letters (letters must be selected 'every so often').
'gets' becomes 'earns' (earning is a kind of getting).
The alternating letters of 'orderly' are 'rel'.
'rel'+'earns'='RELEARNS'
Can you help me to learn more?
(Another definition for relearns that I've seen is " Once more finds out".)