Out of practice, head of firm removed (5)
I believe the answer is:
rusty
'out of practice' is the definition.
(synonyms)
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for rusty that I've seen before include "(Of iron) affected by damp" , "Antiquated" , "Oxidised, corroded" , "Affected by corrosion - out of practice" , "Having a reddish-orange oxide coating" .)