Outsize builder's ledge round room for electronic instrument (12)
I believe the answer is:
oscilloscope
'instrument' is the definition.
(I know that oscilloscope is a type of instrument)
'outsize builder's ledge round room' is the wordplay.
'outsize' becomes 'os'.
'builder's ledge' becomes 'cill' (I can't explain this - if you can you should believe this answer much more).
'round' becomes 'o' (round can mean a round object).
'room' becomes 'scope' (as in scope or room for manoeuvre).
'os'+'cill'+'o'+'scope'='OSCILLOSCOPE'
'for electronic' acts as a link.
This may not be right. Some or all of it may be part of another bit of the clue.
Can you help me to learn more?
(Other definitions for oscilloscope that I've seen before include "Laboratory device for viewing waveforms" , "Laboratory instrument" .)