Paint book (6)
I believe the answer is:
primer
I believe this clue is a double definition.
'paint' is the first definition.
(primer is a kind of paint)
'book' is the second definition.
(primer is a kind of book)
(Other definitions for primer that I've seen before include "He charges" , "Educational book" , "Introductory textbook or first coat of paint" , "Initial coat of paint" , "it might be used by one 7 [PAINTING]" .)