Pastoral, rustic (5)
I believe the answer is:
rural
This clue is a double definition.
'pastoral' is the first definition.
(I know that pastoral can be written as rural)
'rustic' is the second definition.
(similar in meaning)
(Other definitions for rural that I've seen before include "Relating to country life" , "living in the countryside" , "Sort of dean" , "Countryfied" , "Bucolic; pastoral" .)