Pays out and relaxes (7)
I believe the answer is:
unwinds
'relaxes' is the definition.
('unwind' can be a synonym of 'relax')
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for unwinds that I've seen before include "Becomes less tense and relaxes" , "Rests and becomes less tense" , "Relaxes; pays out (thread)" .)