Peacekeepers' secretary-general perhaps not confirmed (10)
I believe the answer is:
unofficial
'peacekeepers' secretary-general perhaps' is the definition.
I can't tell whether this definition defines the answer.
'not confirmed' is the wordplay.
'not' becomes 'un' (prefix meaning 'not').
'confirmed' becomes 'official' (similar in meaning).
'un'+'official'='UNOFFICIAL'
Can you help me to learn more?
(Other definitions for unofficial that I've seen before include "off the record" , "description of Grantchester's English rose" , "Not confirmed by authority" , "Unauthorised" .)