Peninsula forming a large part of America (6)
I believe the answer is:
crimea
'peninsula' is the definition.
(I know that Crimea is a peninsula)
'a large part of america' is the wordplay.
'a large part of' becomes 'crime' (I am not sure about this - if you are sure you should give a lot more credence to this answer).
'america' becomes 'a' (common abbreviation - e.g. in organisation names).
'crime'+'a'='CRIMEA'
'forming' is the link.
Can you help me to learn more?
(Other definitions for crimea that I've seen before include "former battleground" , "part of the Ukraine" , "Yalta peninsula" , "European peninsula" , "Peninsula in today's Ukraine, site of an 1853-6 war" .)