People from Zagreb, perhaps, overthrowing Castro (6)
I believe the answer is:
croats
'people from zagreb' is the definition.
I don't know anything about this answer so I can't tell whether this works.
'overthrowing castro' is the wordplay.
'overthrowing' indicates anagramming the letters (I've seen 'overthrown' mean this).
'castro' is an anagram of 'CROATS'.
'perhaps' is the link.
Can you help me to learn more?
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