Perfected and fitted around old city (7)
I believe the answer is:
matured
'perfected' is the definition.
(thesaurus)
'fitted around old city' is the wordplay.
'fitted' becomes 'mated' (I can't explain this - if you can you should give a lot more credence to this answer).
'around' indicates putting letters inside.
'old city' becomes 'ur' (ancient Sumerian city state).
'mated' enclosing 'ur' is 'MATURED'.
'and' acts as a link.
Can you help me to learn more?
(Other definitions for matured that I've seen before include "Developed fully" , "Ripened" , "Developed; grew up" , "Became fully ripe" , "Mellowed" .)