Performer, in revolt, quits unexpectedly (13)
I believe the answer is:
ventriloquist
'performer' is the definition.
(I know that ventriloquist is a type of performer)
'in revolt quits unexpectedly' is the wordplay.
'unexpectedly' indicates an anagram.
'in'+'revolt'+'quits'='inrevoltquits'
'inrevoltquits' anagrammed gives 'VENTRILOQUIST'.
(Other definitions for ventriloquist that I've seen before include "Dummy operator" , "Performer with dummy" , "Voice-thrower" .)