Perhaps trainee used TNT mistakenly (7)
I believe the answer is:
student
'perhaps trainee' is the definition.
I can't tell whether this defines the answer.
'used tnt mistakenly' is the wordplay.
'mistakenly' is an anagram indicator.
'used'+'tnt'='usedtnt'
'usedtnt' anagrammed gives 'STUDENT'.
Can you help me to learn more?
(Other definitions for student that I've seen before include "Undergraduate maybe" , "Trainee" , "One in higher education" , "collegian" , "Eg, undergraduate" .)