Phoney admission of poverty takes in a good man (8)
I believe the answer is:
impostor
'phoney' is the definition.
(thesaurus)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for impostor that I've seen before include "He fraudulently pretends to be someone else" , "phoney!" , "deceitful person" , "One assuming a false character" , "Sit or mop (anag.)" .)