Piano music for duos (5)
I believe the answer is:
pairs
'for duos' is the definition.
('pair' can be a synonym of 'duo')
'piano music' is the wordplay.
'piano' becomes 'p' (musical abbreviation).
'music' becomes 'airs' ().
'p'+'airs'='PAIRS'
(Other definitions for pairs that I've seen before include "Duos" , "Couples" , "golfing matches" .)