Picked a hundred socks (5)
I believe the answer is:
chose
'picked' is the definition.
(I've seen this before)
'a hundred socks' is the wordplay.
'a hundred' becomes 'c' (roman numeral).
'socks' becomes 'hose' (I've seen this before).
'c'+'hose'='CHOSE'
(Other definitions for chose that I've seen before include "Picked" , "Selected" , "Determined" , "article from Paris" , "preferred" .)