Piece of music has magnificent opening (5)
I believe the answer is:
chasm
'opening' is the definition.
(I know that chasm is a type of opening)
'piece of music has magnificent' is the wordplay.
'piece of' indicates a hidden word.
'CHASM' is hidden in the letters of 'music has magnificent'.
(Other definitions for chasm that I've seen before include "Great divide" , "Deep hole" , "Wide gap" , "rent" , "One yawns" .)