Piles them up in library storage area (6)
I believe the answer is:
stacks
'piles' is the definition.
(pile can mean a stack of something)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for stacks that I've seen before include "Orderly heaps as of hay" , "bags?" , "A lot (of hay?)" , "Orderly piles or heaps" , "Large tall chimneys" .)