Pilot uses infrared navigating to capital city (7)
I believe the answer is:
tripoli
'to capital city' is the definition.
(capital city of Libya)
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for tripoli that I've seen before include "Libyan city" , "North African port" , "Middle East port" , "Place in Libya" , "North African city" .)