Pith helmet: most superior one (4)
I believe the answer is:
topi
'pith helmet' is the definition.
(synonyms)
'most superior one' is the wordplay.
'most superior' becomes 'top'.
'one' becomes 'i' (Roman numeral).
'top'+'i'='TOPI'
(Other definitions for topi that I've seen before include "African antelope" , "that goes ahead" , "Pith helmet" , "Pith-helmet" , "cover in the heat" .)