Porcelain cap (hat in America) (5,5)
I believe the answer is:
crown derby
'porcelain' is the definition.
(I've seen this before)
'cap hat in america' is the wordplay.
'cap' becomes 'crown' ('crown' can be a synonym of 'cap').
'hat in america' becomes 'derby' (I am not sure about this - if you are sure you should give a lot more credence to this answer).
'crown'+'derby'='CROWN DERBY'
Can you help me to learn more?
(Other definitions for crown derby that I've seen before include "China? - with 22a" , "Service" , "Brand of china" , "type of porcelain" , "Kind of porcelain" .)