Port wine from Spain, 60% of it (3)
I believe the answer is:
rio
'port' is the definition.
(Rio de Janeiro is a port)
I don't understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for rio that I've seen before include "place of carnival" , "Manchester United player in South American city, in short?" , "Port, -- de Janeiro" , "... Grande, ... de Janeiro" , "- Ferdinand, footballer" .)