Possibly hot stuff a rural dean expressed is essential (4)
I believe the answer is:
must
'is essential' is the definition.
(similar in meaning)
I don't understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for must that I've seen before include "Prerequisite" , "The mould is compelled" , "Unfermented wine" , "The imperative for mould" , "Is obliged to" .)