Post money for gamble (5)
I believe the answer is:
stake
This clue could be a double definition.
'post money' is the first definition.
'stake' can be an answer for 'post' (synonyms). I am not sure about the 'money' bit.
'gamble' is the second definition.
(stake is a kind of gamble)
'for' is the link.
Can you help me to learn more?
(Other definitions for stake that I've seen before include "Post; money wagered" , "A wager or pointed pole" , "Keats (anag.)" , "Post; gamble" , "Wooden post; ante" .)