Pouring out a copita with the pudding (7)
I believe the answer is:
tapioca
'pudding' is the definition.
(tapioca pudding is a kind of pudding)
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for tapioca that I've seen before include "I act OAP (anag) - edible substance made from cassava" , "Starchy dish" , "Substance from cassava used to thicken puddings" , "it thickens" , "Starch from cassava used in making puddings" .)